If you already have an email in outlook you can edit or remove the account.
First start outlook and select Tools and then Account Setting  from the top menu.
 
 
 
 
 
 
From the open window  you can choose the account you want to edit and then click on remove or edit. For adding a new account click on New button.  For see the steps click 
here.
 
 
 
 
 
 
 
For reach the accounts  in Outlook 2010 select file and then Account Settings. The other steps are the same.
 
 
 
 
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